Application of the Euler characteristic to the study of homopolymer blends and copolymer melts
Polimery 2001, No 5, 307
SummaryThe Euler characteristic is applied to study the phase separation/ordering phenomena occurring in polymer mixtures. Several methods used to compute Euler characteristics are described and discussed in terms of accuracy and efficiency. A novel, robust and exact algorithm based on simplex decomposition is presented. The simulated morphology of spinodal decomposition and the phase equilibrium diagram of gradient copolymers are analyzed in terms of Euler characteristics. Again, the Euler characteristics are applied to specify the connectivity of bicontinuous patterns, to distinguish the disperse and the bicontinuous morphologies, and to detect the percolarion transition. During the spinodal decomposition, the dynamic transformation between the bicontinuous and the droplet patterns is shown to involve the formation of a transient "cylindrical" morphology.
Keywords: spinodal decomposition, phase separation, Euler characteristic, homopolymer blends, gradient copolymers, morphology