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J. Bucheńska, T. Skwarski


Determination of hydroperoxide groups in oxidized polyamide parts


Polimery 1990, No 11-12, 447



DOI: dx.doi.org/10.14314/polimery.1990.447


Summary

The possibility of initiating graft copolymerization by the introduction of reactive hydroperoxide groups and peroxide groups into polyamide chain by direct oxidation with air oxygen has been investigated. The effect of time and temperature of oxidation on the amount of forming and decomposing hydroperoxide groups has been investigated. The rate constants and average energy of activation of decomposition of hydroperoxide groups have been calculated. This energy of activation is equal to 48.28 kJ/mol.


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