Kinetics of the vulcanization process. Part III. Range of Scheele's model applicability
Kinetics of the vulcanization process.
Part III. Range of Scheele's model applicability
It has been found that Scheele's model can be used for the description of the vulcametric curve of rubber compounds heated during a time shorter than 3 tmax a tatemperature up to 443 K. The application of the Marquardt's non-linear estimation for assigning both the crosslinking and degradation rate constants, reduces significantly the error in their calculation.
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