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B.Jurkowski, J.Kubis

Kinetics of the vulcanization process.

Part III. Range of Scheele's model applicability

Polimery 1980, No 10, 370

DOI: dx.doi.org/10.14314/polimery.1980.370


It has been found that Scheele's model can be used for the description of the vulcametric curve of rubber compounds heated during a time shorter than 3 tmax a tatemperature up to 443 K. The application of the Marquardt's non-linear estimation for assigning both the crosslinking and degradation rate constants, reduces significantly the error in their calculation.

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