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W. Kuran

Mechanism of stereoregulation in coordination polymerization of hydrocarbon monomers.

Part. II. Polymerization of conjugated dienes

Polimery 1995, No 3, 137

DOI: dx.doi.org/10.14314/polimery.1995.137


Stereospecific polymerization of conjugated dienes by Ziegler–Natta and related coordination catalysts has been reviewed in terms of the structure of active sites and the stereocontrol mechanism. From this point of view, the following topics have been discussed in detail: formation of isotactic and syndiotactic ds-1,4-polydienes, formation of syndiotactic and isotactic 1,2- polydienes and formation of trans-1,4 polydienes as the result of anti–syn isomerization.

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