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M. Bratychak, J. Pielichowski

Modification of bisphenol-A epoxy resins with nitrogen – containing peroxide compounds

Polimery 1993, No 4-5, 170

DOI: dx.doi.org/10.14314/polimery.1993.170


By modification of a bisphenol-A epoxy resin with N-methyl- erfbutylperoxyethanolamine or N-di((ert-butylperoxymcthyl)ethanolamine some nitrogen – ontaining peroxyoligomers were prepared. The chemical structure of these compounds was confirmed by methods of chemical analysis and IR- and NMR-spectroscopy. Thermal stability of these oligomers was also determined and the possibility of using them for the preparation of compositions crosslinked with unsaturated oligoesters was established. The crosslinking mechanizm of these compositions was elucidated.

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