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W. Kuran, T. Listoś


Polymerization of oxiranes and their copolymerization with CO2, alkylene carbonates and cyclic anhydrides

by coordination catalysts


Polimery 1993, No 8-9, 366


DOI: dx.doi.org/10.14314/polimery.1993.366

Summary

A comprehensive review of mechanisms of the oxirane polymerizations and copolymerizations by coordination catalysts was presented. A particular attention was paid to the nature of active centres of catalysts and to the oxirane ring-opening mechanism. Further interest was devoted to the mechanism of oxirane copolymerization with carbonyl monomers such as C02 and heterocycles with an exocyclic oxygen atom.


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