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L.A. Rishina, E.I. Vizen, L.N. Sosnovskaya


Stereospecific propylene polymerization on titanium-magnesium catalysts


Polimery 1986, No 10, 380



DOI: dx.doi.org/10.14314/polimery.1986.380

Summary

The kinetics of stereospecific propylene polymerization on the TiCl4-MgCl2 system with a donor additive of p-methoxy-ethylbenzoate was investigated. The catalyst activity is equal to 100 kg PP/g Ti-h and the isotactic index of polypropylene is greater than 90 wt %. The mechanism oi the aonor additive action on the course of polymerization has been explained. Propylene has also been polymerized in the presence of a TiCl4-MgCl2 system containing as a polymeric support polyethylene grafted with poly-4-vinylpyridine. In the presence of this polymeric support, polypropylene was obtained with a lower content of dust fraction and with a higher diameter of polymer particles.


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