Studies on the copolymerization process of silanes with components of the unsaturated polyester resins.
I. Homopolymerization of vinyltris(β-methoxyethoxy)silane and its copolymerization with styrene
A literature review of works concerning the radical homopolymerization of vinylsilanes and their copolymerization with styrene has been presented. The homopolymerization proces of vlnyltris(β-methoxyethoxy)silane and its copolymerization with styrene has been carried out at 130°C in the presence of tert-butyl perbenzoate as an initiator. The c om position of copolymers has been determined, reactivity ratios of silane and styrene calculated and the dependence of the reaction rate, Vbr, on the initial ratio of comonomers characterized.
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