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Z.K. Brzozowski, I. Zadrożna, E. Lato

Studies on the synthesis of polyarylales with allylic side-groups. Part I. Polyarylates from

2,2-bis(3-allyl-4-hydroxyphenyl)propane and isophthaloyl chloride

Polimery 1993, No 8-9, 419

DOI: dx.doi.org/10.14314/polimery.1993.419


Conditions of synthesis of diallyl derivatives of bisphenol-A via Claisen rearrangement reaction and of preparation of polyarylates from these derivatives via intcrfacial polycondensation with isophthaloyl chloride were established. By the methods of 1H-NMR, IR, and UV/Vis spectroscopy and elementary analysis, the structure of polymers was confirmed. The results of intrinsic viscosity determinations and thermal analysis revealed high molecular weight and a considerable thermal resistance of these polyarylates.

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