Synthesis of cationicpolyelectrolytes. Part II. The effect of the process parameters on the course
of polymerization of diallyldimethylammonium chloride
The effect of monomer concentration (25—50 percent), typeand amount of persulphate initiator ((NH4)2S2O6and Na2S2O6), initial pH-value of the reactionmixture (2.8–8.0). The presence of Na2EDTA (50–300 ppm), type of solvent (H2O,DMF, DMSO) and temperature (30–80°C) on the course of polymerization of diallyldlmethylammoniumchloride has been investigated. The conditions of the synthesis of cationicpolelectrolytes based on diallyldimethylammonium chloride have been establishedto obtain polymer of low molecular mass in a relatively high yield.
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