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M.F. Sorokin, Z.A. Kocnova, L.N. Finjakin


The manufacturing process of epoxide oligomers from various bisphenols


Polimery 1986, No 3–4, 93



DOI: dx.doi.org/10.14314/polimery.1986.093

Summary

On the example of model reactions of phenol and ortho-N-methylamidophenol with epichlorohydrin in alkaline medium, the effect of bisphenol acidity on the kinetics of epoxide oligomer synthesis has been investigated. A system of a series of subsequent and parallel reactions has been proposed to describe the mechanism of this synthesis. Process has been simulated with computer and a good coincidence of the calculated and experimental reaction rate constants for the individual elementary reactions has been observed.


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