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H. Maciejewski, K. Szubert, B. Marciniec

Technologies of functionalized polysiloxanes preparation

Polimery 2009, No 10, 626


Summary

The paper is a review of technologies of preparation of polysiloxanes via hydrosilylation reaction catalyzed with rhodium complex [{Rh(μ-OSiMe3)(cod)}2] immobilized in ionic liquid (Scheme A). The assumptions and parameters of the process are presented (Table 1). The syntheses of functionalized polysiloxanes basing on epoxyfunctional silicone precursors were discussed as well as selected applications of such precursors for preparation of new materials.


Key words: hydrosilylation, functionalized silicones, epoxyfunctional siloxanes, hybrid materials


e-mail: maciejm@amu.edu.pl


H. Maciejewski, K. Szubert, B. Marciniec

Technologies of functionalized polysiloxanes preparation