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B. Thomalla, J. Thomalla

The role of acetoacetic groupings in the production of varnish and adhesive sealants.

Part I. The use of acetoacetic groupings in the chemistry of macromolecular compounds

for making varnish and adhesive sealants

Polimery 1999, No 1, 6

DOI: dx.doi.org/10.14314/polimery.1999.006


Preparation of copolymers involving mers containing acetoacetic side groupings is reviewed. In linear macromolecular compounds crosslinked, such groupings expand the field of applications, especially as regards modern varnishes and adhesive sealants. The chemical courses of crosslinking of polymers and resins containing acetoacetic groupings (Michael reaction, reactions with diamines and diisocyanates, use of enamines) and acetylacetonation of resins with hydroxyl groups (e. g., ofpolyesters) are presented.

Keywords: polymers and resins containing acetoacetic groupings, crosslinking with participation ofacetoacetic groupings, varnish products

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